Selective Recognition of Fe3+ by a Simple Schiff Base Chemosensor

Colorimetric and Optical Discrimination of Halides by a Simple Chemosensor.

A thiophene-based tripodal copper(II) complex has been synthesized as a new colorimetric and optical chemosensor for naked-eye discrimination of halides in acetonitrile and an acetonitrile-water mixture. The binding interactions of the new receptor with several anions were analyzed by UV-Vis titrations, electrospray ionization mass spectrometric (ESI-MS) experiments and density functional theor...

Highly efficient catalyst for removal of heavy metal ions modified by a novel Schiff base ligand

An alomina-based nano adsorbent was prepared by modification of the external surface of γ-alumina (γ-Al2O3) nanoparticles with functional groups of a new Schiff base 4-[(2-hydroxy-3-methoxy-benzylidene)-amino]-5-methyl-2,4-dihydro-[1,2.4]triazole-3-thione] “L”. In order to the removal of Cr(VI) from aqueous solutions, we used the reaction of the sodium dodecyl sulfate coated nano-alumina with L...

Microwave-assisted Decomposition of two Simple Zinc(II) Schiff Base Complexes: A Facile and Fast Route to Synthesize ZnO Nanostructures

ZnO nanorods and nanoparticles have been easily prepared via the decomposition of two simple Schiff base zinc (II) complexes, namely (N,N'–disalicylalethylenediamine)zince(II) and (N,N'–disalicylalphenylenediamine)zince(II) under microwave irradiation. The decomposition products of the complexes were characterized by FT-IR, XRD, SEM, EDX and UV-visible spectroscopy.  FT-IR, XRD and EDX results ...

synthesis of a novel fluorescent schiff base as a possible hg and ag ions selective sensor

Experimental and theoretical characterization of a new Schiff-base ligand

Here, new N,N′-dipyridoxyl(4,4''-diaminodiphenylether) Schiff-base ligand has been synthesized and characterized by IR, 1H NMR and mass spectrometry. Also, geometry optimization and theoretical assignment of IR spectrum of the ligand have been computed by employing density functional theory (DFT) method. Two pyridine rings and benzene rings in the bridge region are not in the same plane. The ca...